- Electron-spin-echo - Big Chemical Encyclopedia.
- Geometric spin echo under zero field | Nature Communications.
- Electron Spin Echo Envelope Spectrometry: Review of Scientific.
- The return of the spin echo - P.
- Spin Echo - an overview | ScienceDirect Topics.
- Electron spin echo and spin relaxation of low-symmetry Mn2.
- Electron Spin Echo Methods in Photosynthesis Research.
- Spin Echo of a Single Electron Spin in a Quantum Dot.
- Spin-Orbit Echo - Science.
- Electron-Spin-Echo Envelope Modulation - NASA/ADS.
- Electron spin echo studies of the location and coordination of metal.
- Electron spin echo detection of stochastic molecular librations: N….
- Electron spin echo envelope modulation studies of water bound to.
- Electron Spin Echo and Coherence Times in Silicon Carbide.
Electron-spin-echo - Big Chemical Encyclopedia.
Electron spin echo electron-nuclear double resonance (ESE-ENDOR) experiments performed on a broad radical electron paramagnetic resonance (EPR) signal observed in photosystem II particles depleted. A system is described for recording the envelope of electron spin echoes and for obtaining the superhyperfine splitting of the electron resonance interval from the form of the envelope. The envelope modulation property on which this system depends is summarized briefly, the microwave system and logic systems used to record the envelope are described, and the problems encountered in making a.
Geometric spin echo under zero field | Nature Communications.
An electron with spin parallel to the external field has lower energy than an electron with antiparallel spin. In addition, the difference between this energy gap increases with the applied field. The equation governing the energy difference in a spin 1 2 system is DE =g em BB 0; (1.1) where g e is the electron spin g-factor for free electrons (g. Pulsed electron-electron double resonance techniques such as the four-pulse double electron-electron resonance expt. measure a dipolar evolution function of the sample. For a sample consisting of spin-carrying nanoobjects, this function is the product of a form factor, corresponding to the internal structure of the nanoobject, and a background. AB - The site locations and adsorbate interactions of Cu2+ in Cu2+-exchanged synthetic clinoptilolite have been determined by electron spin resonance and electron spin echo modulation spectroscopes. Strong effects of the H+, Li+, Na+, and K+ cocations have been found on the coordination number and on the location of the cupric ion.
Electron Spin Echo Envelope Spectrometry: Review of Scientific.
. In the 46 years since its discovery in Ce(III)-doped CaWO 4 single crystals, electron spin echo envelope modulation (ESEEM) spectroscopy has developed into an important method for the characterization of paramagnetic centers. The capability of ESEEM to resolve ligand hyperfine couplings to paramagnetic transition metal ions in powder or frozen solution samples, and its sensitivity to the.
The return of the spin echo - P.
Electron spin echo modulation analysis of photoproduced radical cation locations in micelles and vesicles. International Journal of Radiation Applications and Instrumentation. Part C. Radiation Physics and Chemistry 1991, 37 (5-6) , 629-633. (91)90160-4 M. Mostafavi, J.L. Marignier, J. Amblard, J. Belloni. Electron spin echo envelope modulation (ESEEM) spectroscopy has been applied to the determination of the number of water molecules coordinated to the metal in the binary complex of staphylococcal nuclease with Mn2+, to the ternary enzyme-Mn2+-3',5'-pdTp complex, and to ternary complexes of a number of mutant enzymes in which metal-binding.
Spin Echo - an overview | ScienceDirect Topics.
Electron Spin Echo Envelope Modulation (ESEEM) spectroscopy is a powerful technique for the study of hyperfine interactions between an unpaired electron and nearby nuclei in solids, and is employed in quantitative structural studies. Here, we describe the use of ESEEM to study the slow motion of deu. Electron Spin Echo Spectroscopy and Photosynthesis You are accessing a document from the Department of Energy's (DOE) OSTI.GOV. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy science and technology. Authors..
Electron spin echo and spin relaxation of low-symmetry Mn2.
Summary. Electron spin echo methods allow photosynthesis researchers to probe the local structure of paramagnetic transition metal and organic radical centers. In particular the electron spin echo methods of electron spin echo envelope modulation (ESEEM) and electron spin echo — electron nuclear double resonance (ESE-ENDOR) are used to measure.
Electron Spin Echo Methods in Photosynthesis Research.
Electron spin echo (ESE) spectroscopy of spin-labeled molecules allows detecting their restricted stochastic rotations (stochastic molecular librations). As in molecular disordered media motions may be highly cooperative, it would be desirable to investigate their spectroscopic manifestation also in the systems where cooperative effects would be certainly ruled out. In magnetic resonance, a spin echo is the refocusing of spin magnetisation by a pulse of resonant electromagnetic radiation. The spin echo spectrometer possesses an extremely high energy resolution. Additionally, it measures the density-density correlation F as a function of momentum transfer Q and time. Other neutron scattering techniques measure the dynamic. The electron free-precession beats are measured conveniently in terms of the electron-spin-echo envelope modulation pattern obtained from the two-pulse echo experiment. The theory of the effect is developed for purely magnetically coupled nuclei and is confirmed by electron-spin-echo measurements of paramagnetic Ce 3+ in CaWO 4 , where the 14%.
Spin Echo of a Single Electron Spin in a Quantum Dot.
Spin echo is widely used in bulk electron spin resonance (ESR) experiments to study interactions and to determine the structure of complex molecules ().Recently, local contact interactions were observed between single-NV electronic spins and the nuclear spins associated with the host nitrogen and the nearest-neighbor carbon atoms (3, 24). Electron spin echo envelope modulation studies aimed at characterizing the superhyperfine coupling between protons of axially bound water molecules and the nickel ion in Ni III (CN) 4 (H 2 O) 2-were carried out. X-band, two-pulse ESEEM experiments showed that this coupling is characterized by a large anisotropic component resulting in 0.1-1.6-MHz shifts of the v α + v β proton sum.
Spin-Orbit Echo - Science.
An electron spin echo envelope modulation frequency analysis is performed of the 14 N and 15 N bacteriochlorophyll a + cation in solid solution. Hyperfine couplings of 2.0 and 3.1 MHz are derived which correspond to the perpendicular component of the axial hyperfine coupling tensor. Seven quadrupole frequencies were measured, six of which group.
Electron-Spin-Echo Envelope Modulation - NASA/ADS.
Spin-Echo Wikipedia. Electron spin echo detection of stochastic molecular librations:. Electron Spin Echo Envelope Modulation Spectroscopy. Intoduction to Coupling Constant - Spin 1 2. Electron Spin Echo and Coherence Times in Silicon Carbide. Comparison of 250 MHz electron spin echo and continuous wave oxygen EPR. EOF. Quantum pyramid.
Electron spin echo studies of the location and coordination of metal.
Fig. 1 (A) The electron spin (red arrows) changes its direction at and between scatterings by impurities (x symbols) in the presence of the SOI; the twisted spin (blue arrows) does not change.(B) Spin-orbit echo.Multiple impurity scatterings cause the diffusive motion of the electron, and the total spin (red arrows) decays in the presence of a constant SOI λ [stages (i) to (iv)]. We report a measurement of the spin-echo decay of a single electron spin confined in a semiconductor quantum dot. When we tip the spin in the transverse plane via a magnetic field burst, it dephases in 37 ns due to the Larmor precession around a random effective field from the nuclear spins in the host material. We reverse this dephasing to a large extent via a spin-echo pulse, and find a spin.
Electron spin echo detection of stochastic molecular librations: N….
Spin-echo full-intensity acquired localized spectroscopy. The spin-echo full-intensity acquired localized (SPECIAL) spectroscopy is a hybrid sequence, which achieves localization by removing one refocusing 180-degree pulse in the PRESS sequence and adding one-dimensional ISIS. One-dimensional ISIS uses an adiabatic 180-degree pulse for a better.
Electron spin echo envelope modulation studies of water bound to.
A variation of the electron spin echo (ESE) signal caused by laser pulse in a blend of [6,6]-phenyl C61 butyric acid methyl ester and poly(3-hexylthiophene) (P3HT:PCBM) was detected. This variation was attributed to light-generated paramagnetic species in P3HT:PCBM blend, with non-equilibrium spin polarization. The echo-detected electron paramagnetic resonance (EPR) spectrum of these species. Electron spin echo envelope modulation (ESEEM) spectroscopy as a tool to investigate the coordination environment of metal centers. Coordination Chemistry Reviews 2000, 204 (1) , 1-112. (99)00218-0 Zbigniew Sojka, Michel Che. Catalytic chemistry of transition metal ions on oxide surfaces.
Electron Spin Echo and Coherence Times in Silicon Carbide.
Electron paramagnetic resonance. Electron paramagnetic resonance ( EPR) or electron spin resonance ( ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spins excited are those of the electrons instead of the atomic nuclei. Electron-spin echo envelope modulation (ESEEM) spectroscopy is a pulsed technique that detects weak hyperfine and quadrupolar couplings in the solid state. It is complementary to ENDOR in that it gives the best results in the intermediate regime of hyperfine couplings where A ≈ ν N ; in addition, it is particularly sensitive to couplings with quadrupolar nuclei such as 2 H and.
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